Molecular-Shape: Molecular Orbital Theory
Its All about Pj Problem Strings (SiPjAjk) - 7 Spaces Of Interest and their associated Basic Sequences; 7 Pj Problems of Interest (PPI) and their Alleles (Ajk)
1. Why Is there molecular orbital theory given that there exist valence bond theory?
Valence bond theory and hybrid orbitals does not explain all aspects of bonding. For example, it does not successfully describe the excited states of molecules. A scenario involved in molecular light absorption and the resultant color emission.
2. What is the Difference between atomic orbitals and molecular orbitals?
Ans: Atomic orbitals are the wave functions that describe the proble location of electrons in atoms. Molecular orbitals are the wave functions that describe the proble locations of the electrons in the context of molecules. Most of the concepts in atomic orbitals theory carry-over to molecular orbital theory (abbreviated as MO). The primary difference is that MOs are associated with the entire molecule instead of a single atom.
3. (a) Use the atomic orbitals of the hydrogen atom (H), to obtain the molecular orbitals for the hydrogen molecule (H2). Hints: whenever two atomic orbitals overlap, two molecular orbitals form.
(b) Draw the Energy-Level Diagram representing the atomic orbitals -molecular orbitals interaction of problem 3(a).
Ans: 3(a) The 1s atomic orbitals of the two hydrogen atoms overlap to form two molecular orbitals (figure 1). One of the molecular orbitals has its wave function concentrated between the nuclei of the atoms, that is, the electrons are more likely to be found in this region and thus more likelely to bond. This molecular orbital is called the bonding molecular orbital. The strong mutual nucleic pull on the electrons in the bonding molecular orbital establishes a strong covalent bond (σ1s bond) between the electrons and thus a stable hydrogen molecule. In other words, the electron is more stable in the bonding molecular orbital than it is in its 1s atomic orbital. This stability is associated with lower energy state (figure 1b). The wave function in the other molecular orbital is scantily distributed in the region between the nuclei and highly distributed on opposite sides of the nuclei. As a result, there is little electron density in the region between the nuclei and a low likelihood of electron bonding. This molecular orbital is called the antibonding molecular orbital. In the antibonding molecular orbital atomic orbitals cancel each other instead of enhancing each other. The electron is repelled from the bonding region and as a result it is less stable (i.e, it has higher energy) than it is in the 1s atomic orbital.
(b) Atomic - molecular orbitals interaction is often represented by the energy-level diagram (also called molecular orbital diagram). Figure 2 is the energy-level diagram for the hydrogen molecule (H2).
4. Write the general representative string for the excitation of one of the electrons of the hydrogen molecule by light from the bonding MO (σ1s) to the antibonding MO* (σ1s*.
The excited electron is pushed away from its bonding molecular orbital and further repelled in the antibonding molecular orbital. Thus the general representative string is S7P3A32 (force-push in a multi-matter multi-dynamic space).
5. Use the respective bond order of hydrogen (H2) and helium (He2) molecules to predict the stability of diatomic hydrogen molecule and the instability of diatomic helium molecule.
Ans: 5. The bond order is defined in molecular orbital theory as follows:
(1/2)[number of bonding electrons - antibonding electrons].
A bond order of 1 represents a single bond; a bond order of 2 represents a double bond; and a bond order of 3 represents a triple bond.
Hydrogen (H2) has 2 bonding electrons and 0 antibonding electrons.
So its bond order = (1/2)[2 - 0] = 1. Therefore, H2 is stable.
Helium (He2) has 2 bonding electrons and 2 antibonding electrons.
So its bond order = (1/2)[2 - 2] = 0.
A bond order of 0 implies no bond exists. Therefore, He2 is not stable
The point . is a mathematical abstraction. It has negligible size and a great sense of position. Consequently, it is front and center in abstract existential reasoning.
The Periodic Table
Ordinary Differential Equations (ODEs)